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EMBRITTLEMENT OF Fe-Cr-Al ALLOYS AND EFFECT OF Y ADDITION

LI Bei WU Shuangxia LI Dianchen Baotou Research Institute of Rare Earth Ministry of Metallurgical Industry , Baotou , ChinaMA Ruzhang University Science and Technology Beijing , Beijing , China Baotou Research Institute of Rare Earth , Ministry of Metallurgical Industry , Baotou 014010 , China

金属学报(英文版)

A high temperature embrittlement occures in Fe-15Cr-4AI and Fe-20Cr-4Al alloys treated over 1000 C.It is caused mainly by 475℃ brittleness during cooling.When a secondary treatment at 500℃ was conducted,the 475℃ brittleness developed very rapidly.After only 15 rain of the treating,little plasticity was remained for all samples pretreuted at the temper- atures over 1000℃ and cooled in water.However,no 475℃ brittleness was generated when pretreating temperature was below 1000℃,Addition of Yttrium can inhibit not only grain growth,but also 475℃ brittleness.For the alloys with 0.2—0.4 wt-%Y,after treating at 800—1300℃,the plasticity did not decrease and the properties of furnace cooled samples were not lower than those of water cooled samples.

关键词: Fe-Cr-Al alloy , null , null

EFFECTS OF IMPURITIES AND RARE EARTH ADDITION ON THE TOUGHENING LEVELS OF Al-Li BASED ALLOYS 2090 AND 1420

L.Meng , T.P.Tu , Y.Z.Yang , M.S.Liu(Department of Materials Science and Engineering , Zhejiang University , Hangzhou 310027 , China)

金属学报(英文版)

The effects of the impurities Fe, Si, Na, K and a rare earth addition, Ce, on the intrinsic and extrinsic toughening levels have been investigated for the Al-Li based alloys 2090 and 1420. 29K reduction in the toughening level for the alloy 2090 with impurities 0.42% Fe+Si or 0.0132% Na+K i4 identified to be caused by the impurities.An improvement on the fracture toughness can be made by adding 0.05%-0.25% Ce to the alloy 2090. The reason behind this is that Ce microalloying can not only enhance both the intrinsic toughening level and the extrinsic toughening level but also suppress the embrittling behavior of the impurities. However, 0.06%-0.15% Ce microalloying fails to bring about any beneficial effect to the toughening level for the alloy 1420.

关键词: Al-Li based alloy , null , null , null

Thermo electrochemistry and its application to metallurgical research

Zheng FANG , Quanru ZHANG , Hengzhong ZHANG , Yuan FANG

材料科学技术(英)

The thermoelectrochemistry (TEC), a novel cross discipline, is presented, including the basic equations for a cell and a half-cell reaction, the treatment of experimental data and its application to electro-generative leaching of mineral and to measuring thermodynamic and kinetic data of an electrode reaction. The TEC technology will play an important part in the research on the metallurgical process under various fields.

关键词:

Metastable phases in rare-earth permanent-magnet materials

Journal of Physics D-Applied Physics

A comprehensive review is given of recent advances in the study of metastable phases in rare-earth permanent magnets. The relations between the structures of the metastable and equilibrium phases and the transformations from the former to the latter are discussed. The formation of the phases is found to depend on the difference between the symmetries of the metastable and equilibrium phases. The magnetic properties of the metastable-phase rare-earth permanent magnets synthesized by various processes, such as mechanical alloying, mechanical milling, rapid quenching, hydrogenation, disproportionation, desorption and recombination, solid-state reaction, solid-gas reaction, self-flux and sputtering, are compared. The main conclusion of this article is that searching for new metastable phases with high magnetic performance will be one of the most active directions in the research on rare-earth permanent magnets.

关键词: fe-c alloys;disproportionation-desorption-recombination;solidified;sm-fe;r = nd;high-coercivity;magnetocrystalline anisotropy;intermetallic compounds;remanence enhancement;crystal-structure;high-performance

EFFECT OF RARE EARTH ON VANADIZATION PROCESS IN BORAX BATH

X.K. Tao , X.Cong , R.S. Peng , J.Liu and Z.Y. Liu Tianjin Institute of Technology , Tianjin 300191 , China

金属学报(英文版)

This paper investigates the effect of rare earth elements on the kinetic process, microstructure and mechanical properties of vanadization in borax bath. The results show that addition of rare earth elements to vanadizing agent has obvious catalytic effect on the rate of vanadization, which has been enchanced by 30%. The wear and corrosion resistance of vanadium carbide layer were prompted by the addition of rare earth to the agent. Through increasing vanadium potential of the agent, activating the surface of workpieces and decreasing the activation energy of diffusion of carbon, rare earth elements accelerate the rate of vanadization process.

关键词: rare earth elements , null , null

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